Process development of flue gas desulphurization wastewater treatment in coalfired power plants towards zero liquid discharge: Energetic, economic and environmental analyses. Xiaoqu Han Dan Zhang Junjie Yan Zhao Shuran Jiping Liu
Wet Desulfurization Technology (WFGD) is the main process for flue gas desulfurization in coalfired power plants in China, mainly including limestonegypsum wet method and seawater desulfurization. At the end of 2014, more than % of the desulfurization equipment was WFGD.
The occurrence of sulfur in coal direct liquefaction residue affects its further high quality and high value utilization. Electrochemical desulfurization is characterized by mild reaction conditions, simple operation, easy separation of sulfur conversion products and little influence on the properties of the liquefied residue. An anodic electrolytic oxidation desulphurization experiment was ...
In 1978, Kirkbride proposed a desulfurization process: the raw coal will be properly pulverized, dried to remove free water, mixed with hydrogen and then treated by microwave radiation. H 2 reacts with S, N and O in coal producing H 2 S, NH 3 and water vapor thus achieving the purpose of desulfurization. The coal shall be as dry as possible ...
The process involves the treatment of crushed coal with an aqueous leaching solution of ferric sulfate which reacts with the coal pyrites to yield soluable ferrous sulfates and elemental sulfur. The solution is drained off and the leaching solution can be regenerated with the production of calcium sulfate (gypsum) and iron oxides.
The flue gas desulfurization (FGD) plant removes sulfur dioxides (SO 2) from flue gas produced by boilers, furnaces, and other sources. Mitsubishi Power effectively contributes to the prevention of air pollution through its wet limestonegypsum FGD process and seawater FGD process, and both processes can treat a large range of SO 2 ...
Mechanism of Pyrite Microbial Desulfurization. The oxidation process of coal conversion is possible by microorganisms after getting influenced by the polyfunctional coal structure and this process usually depends on two main factors: size or shape of coal and surface properties of microorganisms (Konishi et al. 1990). The morphology and ...
Biological desulfurization processes as well as microbial coal desulfurization are called as one of precombustion coal desulfurization processes. The biodesulfurization can be described as microbiological sulfur removal from coal under ambient temperature and pressure without reducing calorific value (Kilbane et al. 2002).
During the desulfurization process of coalfired power plants, there are many related parameters that affect the desulfurization efficiency. So it is very difficult to measure the desulfurization efficiency directly. In this paper, in order to reflect the relationship between monitoring process parameters and desulfurization efficiency better, a novel prediction model of desulfurization ...
In this paper, a twostep desulfurization process for highsulfur coal was investigated. Two Chinese coals with the addition of 10 wt % potassium hydroxide or sodium hydroxide were pyrolyzed under an atmosphere of nitrogen or hydrogen in a fixedbed reactor at 600 °C, and then the obtained chars were washed with hot water. The results indicated that, without the addition of an alkali ...
A novel desulphurization process of coal water slurry via sodium metaborate electroreduction in the alkaline system article{Shen2012AND, title={A novel desulphurization process of coal water slurry via sodium metaborate electroreduction in the alkaline system}, author={Yafei Shen and Tonghua Sun and Jinping Jia}, journal={Fuel}, year={2012 ...
The addition of MPS or ZCS can help the materials stratify strictly according to the density to enhance the sorting function. The clean coal ash and sulfur content are reduced to % and %, while the combustible recovery and desulfurization efficiency are up to % and %, respectively, under the optimal condition.
The coal hydrogen production process requires hightemperature steam as a reactant. Coalfired boilers are usually used to provide hightemperature steam. The ammoniabased desulphurization process is an effective technology to remove SO2 in the coalfired flue gas. However, the mass transfer coefficient of SO2 in such an engineered process is not readily available in the literature. In this ...
Flue gas desulfurization systems (FGD) or scrubbers are devices capable of sulfur removal efficiencies between 50% to 98%. Typically the highest removal is achieved by wet scrubbers and the lowest by dry scrubbers. They are used in coalandoil fired combustion units including utility and industrial boilers, municipal and medical waste ...
Physical desulfurization methods can only remove inorganic sulfur and are economical and practical in nature. 14,15 Highgradient magnetic separation technology is an effective method for physical desulfurization, which can be used to deal with fine particles of paramagnetic minerals and is applied to the desulfurization of fine coal (mainly ...
A Study of Experimental and Improved Absorption Model for the Spray Towers of Wet Flue Gas Desulfurization. D. Liu H. Yu. Materials Science, Physics. 2012. The wet flue gas desulfurization has been the most widely used in the coalfired power plants because of high SO2 removal efficiency, reliability and low utility consumption.
Indonesia's coal love affair still aflame despite pledges. A barge carries coal to the dock next to the Suralaya coalfired power plant in Cilegon, in Indonesia's Banten province. Sania sits in ...
A novel approach is developed for desulphurization of fuels or organics without use of catalyst. In this process, organic and aqueous phases are mixed in a predefined manner under ambient ...
Wet flue gas desulfurization technology has become the most widely used desulphurization technology. The researchers have applied analytic hierarchy process to analyze three aspects of desulfurization system in power plant including technology, economy and sustainable development [1]. Abboud et al. [2] gave the detailed economic evaluation on
This paper briefly introduces various methods of coal desulfurization (physical desulphurization, chemical desulfurization, biological desulfurization, etc.) and analyzes some problems existing in each method. The principle and research process of friction electrostatic separation technology and high gradient magnetic separation technology in precombustion desulfurization technology are ...
Engineering. Flue gas desulfurization is commonly known as FGD and is the technology used for removing sulfur dioxide (SO2) from the exhaust combustion flue gases of power plants that burn coal or oil to produce steam for the turbines that drive their electricity generators. Gajendra Singh Research Scholar at IIT Jodhpur AIIMS Jodhpur.
The desulfurization process took place at a pH of 35, the coalparticle size was 7545 μm, the pulp density was 5%, the temperature was 35°C, and the incubation time was 8 h. Chemical studies also revealed a decrease in the ash content and an increase in the calorific value of coal from 6219 cal/g to 6406 and 6315 cal/g, which indicated ...
As a typical industrial byproduct during the flue gas desulfurization process of coalfired, flue gas desulfurization ash (FGDA) with alkali mineral can facilitate the water damage resistance of asphalt mixtures. However, low density and high hydrophilic coefficient of FGDA limit its improvement effect.
An alternative technology is the Alstom NID (Novel Integrated Desulfurization) process, as shown in Figure 3. A principal feature of this system is the Jtube reactor, whose outline is evident in ...
A flue gas desulfurization (FGD) processing unit, generally known as a scrubber, eliminates sulfur dioxide (SO 2) from the exhaust flue gases in power plants in which coal is burnt. Airborne SO 2 forms sulfuric acid (H 2 SO 4) by oxidizing within airborne water droplets, resulting in "acid rain". Due to the stringent environmental emissions ...
Desulphurization of High Sulfur Coal by Mild Pyrolysis Combination with Magnetic Separation. Quanrun Liu H. Xia Guangxu Huang Chuanxiang Zhang M. Ma C. Wan. Materials Science, Chemistry. 2012. In this work, a new desulfurization process of high sulfur coal was designed and examined. The novel process involved pyrolysis of high sulfur coal at ...
Flue gas desulfurization gypsum (FGDG) is an industrial byproduct generated during the flue gas desulfurization process in coalfired power plants. Flue gas desulfurization systems have been used to limit the release of sulfur dioxide from coalfired power plants since the late 1960s, but in the past decade the production of FGDG has ...
Coalfired power plants can improve wet limestone scrubbing with advanced process control. ... The chemical reaction formula for this desulfurization process is: CaCO 3 + SO 2 + 2 H 2 O +½ O 2 ...
Coal combustion is the largest single source of sulfur oxide pollution. Treatment of some major representative coals with aqueous ferric solution removes 40 to 75 percent of the sulfur content through near quantitative oxidation of the pyritic sulfur contained in the coal matrix. Elemental sulfur and iron sulfate are recovered as products ...
In this study, coal fly ash was functionalized, using a simple onestep process (loading with Al3+ and sulfonation), to yield a solid acid catalyst (S/AlCFA) with strong acid sites. The catalyst was then used to produce furfural from xylose in a biphasic system (H2O(NaCl)/tetrahydrofuran). The furfural yield reached 82% at 180 °C60 min with catalyst/xylose ratio of : (w/w).
environment, the desulfurization and denitration of flue gas in the combustion process of coal has become an important step. This work summarizes the desulfurization and denitration ... In the wet desulfurization process, the scaling and blockage of equipment are easy to occur in the process site. In view of the above problems, a calciumsodium ...
Applying FGD to a power plant is in effect installing an additional industrial chemical plant in its own right with large accompanying capital costs and operating costs. For example, a typical 1000 MWe new build coal plant would typically cost £800 million to build. The installation of FGD systems would cost between £75 million and £95 ...
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